Energy level alignment of poly„3-hexylthiophene...: †6,6‡-phenyl C61 butyric acid methyl ester bulk heterojunction
نویسندگان
چکیده
Photoelectron spectroscopy was used to investigate poly 3-hexylthiophene P3HT , 6,6 -phenyl C61 butyric acid methyl ester PCBM , and their blends on various conductive substrates. The study shows a P3HT-rich layer at the top of the P3HT:PCBM blend films. The energy level alignment of the top P3HT changes with the work function of the substrate and the PCBM concentration at the bottom surface of the blend film. The results can be explained using the integer charge transfer model. © 2009 American Institute of Physics. DOI: 10.1063/1.3163056
منابع مشابه
Direct determination of the electronic structure of the poly(3-hexylthiophene):phenyl-[6,6]-C61 butyric acid methyl ester blend
1566-1199/$ see front matter 2010 Elsevier B.V doi:10.1016/j.orgel.2010.07.023 ⇑ Corresponding author. E-mail address: [email protected] (Z.-L. Guan This article focuses on the electronic structure of the poly(3-hexylthiophene):phenyl-[6,6]C61 butyric acid methyl ester (P3HT:PCBM) blend, widely used in bulk heterojunction (BHJ) solar cells. Given the fact that the surface of the blend film i...
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